this is pretty interesting, though I'd like to read the scientific stuff first...the news articles leave a lot of questions.
It's not a surprise that arsenic bonds with oxygen the same way (atomically speaking) that phosphorous does. Its activities, though, cause an ionic imbalance at the equilibrium normally found in "conditions suitable for life". Even in lithotropic biology almost every other organism eventually ends up generating ATP (one of the major phosphate-based "building blocks of life"), and I'm curious how this bacteria got around that. A lot of work has been done in prokaryotic biofilms that utilize arsenic, among other things, to produce electrical reactions. In a lot of these organisms that lack "normal" cell nuclei, it allows for a lot of things that are conducive to life in inhospitable conditions (like the ability to synthesize sulfates in deep ocean trenches, or photosynthesis in high temperatures, etc.). But again, they generally end up producing ATP.
So at the nucleate level for RNA/DNA, it's not a complete shock that the bacteria could form the helical chains with arsenic (when in a phosphorous-depleted environment) like the others. What is a shock is that it was able to thrive on the switch, since arsenic is notorious for its toxicity, even though humans generally have a decent amount floating around inside them at any one point (especially those who chew snuff), or how it was able to shift its genetic wiring to accept arsenic-based helical strains. Fun stuff for the 500# brains to figure out.